4.4
Special Provisions
The
“Special Provisions” are referred to in Column M of the list of Dangerous Goods
and the information contained therein is additional to that shown for the
relevant entry. Where the wording of the special provision is equivalent to
that in the UN Model Regulations the UN special provision number is shown in
parentheses immediately following the air mode special provision number.
A1 This
article or substance may be transported on passenger aircraft only with the
prior approval of the appropriate authority of the State of origin and the
State of the operator under the written conditions established by those
authorities. A copy of the document of approval, showing the quantity
limitations and packing requirements, must accompany the consignment. The
article or substance may be carried on cargo aircraft in accordance with
Columns K and L of the List of Dangerous Goods in Subsection 4.2. Where States,
other than the State of origin and the State of the operator, have lodged a
variation advising that they require prior approval of shipments made under
this Special Provision, approval must also be obtained from these States, as
appropriate.
Note: Where
Special Provision A1 applies to an item in Subsection 4.2 and the “hand” symbol
“☞” is also shown in the left margin;
these items may be accepted for transport by operator(s) on cargo aircraft
provided approval has been received and advance arrangements made with the
operator(s) (see also Subsection 9.0).
A2 This article or substance may be transported on cargo aircraft, only with the prior approval of the appropriate authority of the State of origin and the State of the operator under the written conditions established by those authorities.
Where States, other than the State of origin and the State of the operator, have lodged a variation advising that they require prior approval of shipments made under this Special Provision, approval must also be obtained from the States of transit, overflight and destination, as appropriate.
In each case, a copy of the document(s) of approval, showing the quantity limitations and the packing requirements, must accompany the consignment.
A3 (223) If the chemical or physical properties of a substance covered by this description are such that, when tested, it does not meet the established defining criteria for the class or division listed in Column C, or any other class or division, it is not subject to these Regulations.
A4 Liquids, having a vapour inhalation toxicity of Packing Group I, are forbidden on both passenger and cargo aircraft. Liquids, having a mist inhalation toxicity of Packing Group I, are forbidden on a passenger aircraft. They may be carried on cargo aircraft providing they are packed in accordance with the packing instructions for the Packing Group I substance and the maximum net quantity per package does not exceed 5 L.
A5 Solids having an inhalation toxicity of Packing Group I are forbidden on passenger aircraft. They may be carried on cargo aircraft providing they are packed in accordance with the packing instruction for the Packing Group I substance and the maximum net quantity per package does not exceed 15 kg.
A6 (43) When offered for carriage as pesticides, these substances must be carried under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see 3.6.1.7 and 3.6.1.8).
A7 Not used.
A8 (332) When transported in non friable tablet form, these goods are assigned to Packing Group III.
A9 Alcoholic beverages containing 70% or less alcohol by volume, when packed in receptacles of 5 L or less, are not subject to these Regulations when carried as cargo.
A10 (39) This substance is not subject to these Regulations when it contains less than 30% silicon, or not less than 90% silicon.
A11 (305) These substances are not subject to these Regulations when in concentrations of less than 50 mg/kg (ppm).
A12 (45) Antimony sulphides and oxides which contain 0.5% or less of arsenic calculated on the total weight are not subject to these Regulations.
A13 (47) Ferricyanides and ferrocyanides are not subject to these Regulations.
A14 Not used.
A15 (59) These substances are not subject to these Regulations when they contain 50% or less magnesium.
A16 (52) This substance is not subject to these Regulations when it contains 4 % or less sodium hydroxide.
A18 (66) Mercurous chloride and cinnabar are not subject to these Regulations.
A19 (225) Fire extinguishers under this entry may include installed actuating cartridges (Cartridges, power device of Division 1.4C or 1.4S), without changing the classification of Division 2.2, provided the total quantity of deflagrating (propellant) explosives does not exceed 3.2 g per extinguishing unit.
A20 During the course of transport, this substance must be protected from direct sunlight and all sources of heat and be placed in adequately ventilated areas. A statement to this effect must be included on the Shipper’s Declaration.
Notes:
1. See 8.1.6.11.1 and Appendix C.1 and C.2
for additional information.
2. Packages must have the “Keep Away From Heat” handling label affixed (see 7.2.4.5 and Figure 7.4.G).
A21 (240)
This entry only applies to vehicles and equipment which are powered by wet
batteries, sodium batteries or lithium batteries and which are transported with
these batteries installed. Examples of such vehicles and equipment are
electrically-powered cars, lawn mowers, wheelchairs and other mobility aids.
Vehicles or equipment which also contain an internal combustion engine must be
consigned under the entries Engine,
internal combustion, flammable gas powered or Engine internal combustion, flammable liquid powered or Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as
appropriate. Hybrid electric vehicles powered by both an internal combustion
engine and wet batteries, sodium batteries or lithium batteries, transported
with the battery(ies) installed, must be consigned under the entries UN 3166 Vehicle, flammable gas powered or UN
3166 Vehicle, flammable liquid powered,
as appropriate.
A22 (152) The classification of this substance will vary with particle size and packaging, but borderlines have not been experimentally determined. The appropriate classification must be made using the procedure for the classification of explosives.
A23 (325) In the case of non fissile or fissile excepted uranium hexafluoride, the material must be classified under UN 2978.
A24 The total quantity of explosive substance contained in the shaped charges and the detonating cord must not exceed 10 kg per assembled perforating gun.
A25 (205) This entry must not be used for Pentachlorophenol, UN 3155.
A26 (119) Refrigerating machines include air conditioning units and machines or other appliances which have been designed for the specific purpose of keeping food or other items at low temperature in an internal compartment. Refrigerating machines and refrigerating machine components are considered not subject to these Regulations if containing less than 12 kg of a gas in Division 2.2 or if containing less than 12 L ammonia solution (UN 2672).
A27 (276) This includes any substance which is not covered by any of the other classes but which has narcotic, noxious or other properties such that, in the event of spillage or leakage on an aircraft extreme annoyance or discomfort could be caused to crew members so as to prevent the correct performance of assigned duties.
A28 (135) The dihydrated sodium salt of dichloroisocyanuric acid is not subject to these Regulations.
A29 (138) p-Bromobenzyl cyanide is not subject to these Regulations.
A30 (273) Maneb or maneb preparations, stabilized against self-heating need not be classified in Division 4.2 when it can be demonstrated by testing that 1 m³ of the substance does not self-ignite and that the temperature at the center of the sample does not exceed 200ºC (392ºF), when the sample is maintained at a temperature of not less than 75ºC ± 2ºC for a period of 24 hours.
A31 (141) Products, which have undergone sufficient heat treatment so they present no hazard during transport, are not subject to these Regulations.
A32 Air bags inflators, air bag modules or seat-belt pretensioners installed in conveyances or in completed conveyance components such as steering columns, door panels, seats, etc. which are not capable of inadvertent activation are not subject tot these Regulations.
The
words “Not Restricted” and the Special Provision number must be included in the
description of the substance on the Air Waybill as required by 8.2.6 when an
Air Waybill is issued.
A33 (103) Ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt are prohibited.
A34 (113) The transport of chemically unstable mixtures is prohibited.
A35 This substance is not subject tot these Regulations when:
● mechanically produced, particle size more than 53 microns; or
● chemically produced, particle size more than 840 microns.
A36 The provisions of Special Provision A2 apply to this entry for Packing Group I only, and the provisions of Special Provision A1 apply to this entry for Packing Group II only, as applicable.
A37 This entry is not intended to include Ammonium permanganate, the transport of which is prohibited under any circumstances.
A38 (207) Polymeric beads and moulding compounds may be made from polystyrene, poly (methyl methacrylate) or other polymeric material.
A39 This substance possesses some dangerous explosive properties when transported in large volumes.
A40 (28) This substance may be transported under provisions of Division 4.1 only if it is so packed that the percentage of diluent will not fall below that stated at any time during transport.
A41 Permeation devices that contain dangerous goods and that are used for purposes of calibrating air quality monitoring devices are not subject to these Regulations provided the following requirements are met:
(a) each device must be constructed of a material compatible with the dangerous goods it contains;
(b) the total quantity of dangerous goods in each device is limited to 2 mL and the device must not be liquid full at 55ºC;
(c) each permeation device must be placed in a sealed, high impact-resistant, tubular inner packaging of plastic or equivalent material. Sufficient absorbent material must be contained in the inner packaging to completely absorb the contents of the device. The closure of the inner packaging must be securely held in place with wire, tape or other positive means;
(d) each inner packaging must be contained in a secondary packaging constructed of metal, or plastic having a minimum thickness of 1.5 mm. The secondary packaging must be hermetically sealed;
(e) the secondary packaging must be securely packed in strong outer packaging. The completed package must be capable of withstanding, without breakage or leakage of any inner packaging and without significant reduction in effectiveness:
1. the following free drops onto a rigid, non-resilient, flat and horizontal surface from a height of 1.8 m:
- one drop flat on the bottom;
- one drop flat on the top;
- one drop flat on the long side;
- one drop flat on the short side;
- one drop on a corner at the junction of three intersecting edges; and
2. a force applied to the top surface for a duration of 24 hours, equivalent to the total weight of identical packages if stacked to a height of 3 m (including the test sample).
Note:
Each of the above tests may be performed on
different but identical packages.
(f) the
gross weight of the completed package must not exceed 30 kg.
A42 (249) Ferrocerium (lighter flints), stabilized against corrosion, with a minimum iron content of 10% are not subject tot these Regulations.
A43 (210) Toxins from plant, animal or bacterial sources which contain infectious substances, or toxins that are contained in infectious substances, must be classified as Division 6.2.
A44 The entry chemical kits or first aid kits is intended to apply to boxes, cases, etc. containing small quantities of one or more compatible items of dangerous goods which are used for example for medical, analytical or testing or repair purposes. The packing group assigned to the kit as a whole must be the most stringent packing group assigned to any individual substance in the kit. The assigned packing group must be shown on the Shipper’s Declaration. The only dangerous goods, which are permitted in the kits, are substances which may be transported as:
● excepted quantities as specified in Column F of Table 4.2, providing the inner packagings and quantities are as prescribed in 2.6.A and 2.6.5.1(a);
● limited quantities under 2.7.2.1.
A45 Not used.
A46 Mixtures of solids which are not subject to these Regulations and flammable liquids may be transported under this entry without first applying the classification criteria of Division 4.1, providing there is no free liquid visible at the time the substance is packaged and the packaging must pass a leakproofness test at the Packing Group II level. Small inner packagings consisting of sealed packets or articles containing less than 10 mL of a Packing Group II or III flammable liquid absorbed into a solid material are not subject to these Regulations provided there is no free liquid in the packet or article.
A47 (219) Genetically modified micro-organisms (GMMO) and genetically modified organisms (GMO), packed and marked in accordance with Packing Instruction 959 are not subject to any other requirements in these Regulations.
If GMMO and GMO meet the definition in 3.6 of a toxic substance or an infectious substance and the criteria for inclusion in Division 6.1 or 6.2, the requirements in these Regulations for transporting toxic substances or infectious substances apply.
A48 Packaging tests are not considered necessary.
A49 Other inert material or inert material mixture may be used at the discretion of the appropriate authority of the State of origin, provided this inert material has identical phlegmatizing properties.
A50 Mixtures of solids which are not subject to these Regulations and toxic liquids may be transported under this entry without first applying the classification criteria of Division 6.1, providing there is no free liquid visible at the time the substance is packaged and the packaging must pass a leakproofness test at the Packing Group II level. This entry must not be used for solids containing a Packing Group I liquid.
A51 Irrespective of the limit specified in column J in Subsection 4.2 – List of Dangerous Goods, aircraft batteries up to a limit of 100 kg gross mass per package may be transported. Transport in accordance with this Special Provision must be noted on the Shipper’s Declaration for Dangerous Goods.
A52 (228) Mixtures not meeting the criteria for flammable gases (Division 2.1) must be transported under UN 3163.
A53 (37) This substance is not subject to these Regulations when coated.
A54 (32) This substance is not subject to these Regulations when in any other form.
A55 (142) Solvent extracted soya bean meal containing 1.5% or less oil and 11% or less moisture, which is substantially free of flammable solvent, is not subject to these Regulations.
A56 This entry applies to articles which contain Class 1 explosive substances and which may also contain dangerous goods of other classes. These articles are used as life-saving vehicle air bag inflators or air bag modules or seat-belts pretensioners.
The quantities given in Columns H, J and L of Subsection 4.2 - List of Dangerous Goods refer to the net weight of the finished article.
Note: For the carriage of a vehicle, see Packing Instructions 950, 951
and 952.
A57 Packagings must be so constructed that explosion is not possible by reason of increased internal pressure.
A58 (144) An aqueous solution containing 24% or less alcohol by volume is not subject to these Regulations.
A59 A tyre assembly unserviceable or damaged is not subject to these Regulations if the tyre is completely deflated. A tyre assembly with a serviceable tyre is not subject to these Regulations provided the tyre is not inflated to a gauge pressure exceeding the maximum rated pressure for that tyre. However, such tyres (including valve assemblies) must be protected from damage during transport, which may require the use of a protective cover.
A60 (215) This entry only applies to the technically pure substance or to formulations derived from it having an SADT higher than 75ºC (167ºF) and therefore does not apply to formulations which are self-reactive substances. For self-reactive substances, see Subsection 3.4 and Appendix C.1 of these Regulations. Homogeneous mixtures containing not more than 35 per cent by mass of azocarbonamide and at least 65 per cent of inert substance are not subject to these Regulations unless criteria of other classes or divisions are met.
A61 (168) Asbestos which is immersed or fixed in a natural or artificial binder (such as cement, plastic, asphalt, resins or mineral ore) in such a way that no escape of hazardous quantities of respirable asbestos fibres can occur during transport is not subject to these Regulations. Manufactured articles, containing asbestos and not meeting this requirement, are nevertheless not subject tot these Regulations when packed so that no escape of hazardous quantities of respirable asbestos fibres can occur during transport.
A62 (178) This designation must only be used when no other appropriate designation exists and then only with the approval of the appropriate authority of the State of origin.
A63 Not used.
A64 (306) This entry may only be used for substances that do not exhibit explosive properties of Class1 when tested in accordance to Test Series 1 and 2 of Class 1 (See UN Manual of Test and Criteria, Part 1).
A65 (270) Aqueous solutions of Division 5.1 inorganic solid nitrate substances are considered as not meeting the criteria of Division 5.1 if the concentration of the substances in solution at the minimum temperature encountered in transport is 80% or less of the saturation limit.
A66 Polyester resin kits consist of two components: a base material (Class 3, Packing Group II or III) and an activator (Division 5.2). The organic peroxide must be Type D, E or F, not requiring temperature control that are authorized for transport on passenger aircraft are permitted in the kits. Packing Group II or III is assigned according to the criteria for Class 3, applied to the base material.
A67 Non-spillable batteries meeting the
requirements of Packing Instruction 872 are not subject to these Regulations
if, at a temperature of 55ºC (131ºF), the electrolyte will not flow from a
ruptured or cracked case. The battery must not contain any free or unabsorbed
liquid. Any electrical battery or battery powered device, equipment or vehicle
having the potential of dangerous evolution of heat must be prepared for
transport so as to prevent:
(a) a short circuit (e.g. in the case of
batteries, by the effective insulation of exposed terminals; or in the case of
equipment, by disconnection of the battery and protection of exposed
terminals); and
(b) unintentional activation
The words “Not Restricted” and the Special Provision number must be included in the description of the substance on the Air Waybill as required by 8.2.6, when an Air Waybill is issued.
A68 (272) This substance must not be transported under the provisions of Division 4.1 unless specifically authorized by the appropriate national authority (see
UN 0143).
A69 Articles, each containing not more than 100 mg of mercury, gallium or inert gas and packaged so that the quantity of mercury, gallium or inert gas per package is 1 g or less, are not subject to these Regulations when carried as cargo.
The
words “Not Restricted” and the Special Provision number must be included in the
description of the substance on the Air Waybill as required by 8.2.6, when an
Air Waybill is issued.
A70 Internal combustion or fuel cell engines, being shipped either separately or incorporated into a vehicle, machine or other apparatus, the fuel tank of which has never contained any fuel and the fuel system of which is completely empty of fuel or that are powered by a fuel that does not meet the classification criteria for any class or division and without batteries or other dangerous goods, are not subject to these Regulations.
Flammable gas powered internal combustion or fuel cell engines being shipped without batteries or other dangerous goods either separately or incorporated into a vehicle, machine or other apparatus that have contained fuel but have been flushed, purged and filled with a non-flammable gas or fluid to nullify the hazard are not subject tot these Regulations provided that:
(a) the shipper has made prior arrangements with the operator;
(b) the shipper has provided the operator with written or electronic documentation stating that the flushing, purging and filling procedure has been followed and that the final contents of the engine(s) have been tested and verified to be non-flammable; and
(c) the final pressure of the non-flammable gas used to fill the system does not exceed 200 kPa at 20ºC.
Multiple engines meeting the provisions of this special provision may be shipped in a unit load device or other type of pallet provided that the shipper has made prior arrangements with the operator(s) for each consignment.
When this special provision is used, the words “Not Restricted” and the Special Provision number must be included in the description of the substance on the Air Waybill as required by 8.2.6, when an Air Waybill is issued.
A71 (38) This substance is not subject to these Regulations when it contains 0.1% or less calcium carbide.
A72 (163) A substance specifically listed by name in the List of Dangerous Goods must not be transported under this entry. Materials transported under this entry may contain 20% or less nitrocellulose provided the nitrocellulose contains 12.6% or less nitrogen.
A73 (237) The membrane filters, including paper separators, coating, or backing materials, etc. that are present in transport, must not be liable to propagate a detonation as tested by one of the tests described in the UN Manual of Tests and Criteria, Part I, Test Series 1(a).
In addition, the appropriate authority may determine, on the basis of the results of suitable burning rate tests taking account of the standard tests in the UN Manual of Tests and Criteria, Part III, subsection 33.2.1, nitrocellulose membrane filters in the form in which they are to be transported are not subject to the provisions of these Regulations applicable to flammable solids in Division 4.1.
A74 (169) Phthalic anhydride in the solid state and tetrahydrophthalic anhydrides, with 0.05% or less maleic anhydride, are not subject to these Regulations. Phthalic anhydride molten at a temperature above its flash point, with 0.05% or less maleic anhydride, must be classified under UN 3256.
A75 Articles such as sterilisation devices, when containing less than 30 mL per inner packaging, with not more than 150 mL per outer packaging may be transported on passenger and cargo aircraft in accordance with the provisions in Subsection 2.6 irrespective of 2.6.1 and the indication of “Forbidden” in columns G to L of the List of Dangerous Goods (Section 4.2), provided such packagings were first subjected to comparative fire testing. Comparative fire testing must show no difference in burning rate between a package as prepared for transport (including the substance to be transported) and an identical package filled with water.
A76 In the case of fissile uranium hexafluoride, the material must be classified under UN 2977.
A77 (326) Mixtures of solids which are not subject to these Regulations and corrosive liquids may be transported under this entry without first applying the classification criteria of Class 8, providing there is no free liquid visible at the time the substance is packaged and the packaging must pass a leakproofness test at the Packing Group II level.
A78 Radioactive material with a subsidiary risk must:
(a) be labelled with subsidiary risk labels corresponding to each subsidiary risk exhibited by the material in accordance with the relevant provisions of 10.7.2. Corresponding placards must be affixed to cargo transport units in accordance with the relevant provisions of 10.7.5.
(b) be allocated to Packing Groups I, II or III, as and if appropriate, by application of the grouping criteria in Section 3 corresponding to the nature of the predominant subsidiary risk.
The description required in 10.8.3.9.2(b) must include a description of these subsidiary risks (e.g. “Subsidiary risk: 3, 6.1”), the name of the constituents which most predominantly contribute to this (these) subsidiary risk(s), and where applicable, the packing group.
(c) the packaging must also be capable of meeting the appropriate performance criteria for the subsidiary risk.
Radioactive material with a subsidiary risk of Division 4.2 (Packing Group I) must be transported in Type B packages. Radioactive material with a subsidiary risk of Division 2.1 is forbidden from transport on passenger aircraft and radioactive material with a subsidiary risk of Division 2.3 is forbidden from transport on passenger or cargo aircraft except with the prior approval of the appropriate authority of the State of origin and the State of the operator under the conditions established by those authorities. A copy of the document of approval, showing the quantity limitations and the packaging requirements, must accompany the consignment.
A79 (307) This entry may only be used for uniform mixtures containing ammonium nitrate as the main ingredient within the following composition limits:
(a) not less than 90% ammonium nitrate with not more than 0.2% total combustible/organic material calculated as carbon and with added matter, if any, which is inorganic and inert towards ammonium nitrate;
(b) less than 90% but more than 70% ammonium nitrate with other inorganic materials or more than 80% but less than 90% ammonium nitrate mixed with calcium carbonate and/or dolomite and/or mineral calcium sulphate and not more than 0.4% total combustible/organic material calculated as carbon; or
(c) nitrogen type ammonium nitrate based fertilizers containing mixtures of ammonium nitrate and ammonium sulphate with more than 45% but less than 70% ammonium nitrate and not more than 0.4 % total combustible/organic material calculated as carbon such that the sum of the percentage composition of ammonium nitrate and ammonium sulphate exceeds 70%.
A80 (220) The technical name of the flammable liquid component only of this solution or mixture must be shown in parentheses immediately following the proper shipping name.
A81 The quantity limits shown in Columns J and L do not apply to body parts, organs or whole bodies.
Note:
Blood, urine and other body fluids are not
considered “body parts” for the purposes of this special provision.
☞ Transport in accordance with this Special Provision must be noted on the Shipper’s Declaration for Dangerous Goods.
A82 (177) Barium sulphate is not subject to these Regulations.
A83 (208) The commercial grade of calcium nitrate fertilizer, when consisting mainly of a double salt (calcium nitrate and ammonium nitrate) containing 10% or less ammonium nitrate and 12% or more water of crystallization, is not subject to these Regulations.
A84 (182) The group of alkali metals includes lithium, sodium, potassium, rubidium and caesium.
A85 (183) The group of alkaline earth metals includes magnesium, calcium, strontium and barium.
A86 (241) The formulations must be prepared so that it remains homogeneous and does not separate during transport. Formulations with low nitrocellulose contents are not subject to these Regulations, provided that:
(i) they do not exhibit dangerous properties when tested for their liability to detonate, deflagrate or explode when heated under defined confinement by the tests of Test Series 1(a), 2(b) and 2(c) respectively in the UN Manual of Tests and Criteria; and
(ii) they are not flammable solids when tested in accordance with 3.4.1.1.3 or test N1 in the UN Manual of Tests and Criteria, Part III, subsection 3.3.2.1.4 (chips, if necessary, crushed and sieved to a particle size of less than 1.25 mm).
A87 Articles which are not fully enclosed by packaging, crates or other means that prevent ready identification, are not subject to the marking requirements of Subsection 7.1 or the labelling requirements of Subsection 7.2.
A88 Prototype or low production, (i.e. annual production runs consisting of no more than 100 lithium cells or batteries) lithium cells or batteries that have not been tested to the requirements in subsection 38.3 of the UN Manual of Tests and Criteria may be transported aboard cargo aircraft, if approved by the appropriate authority of the State of origin and the following requirements are met:
(a) except as provided in paragraph (c), the cells or batteries must be transported in an outer packaging that is a metal, plastic or plywood drum or a metal, plastic or wooden box and that meets the criteria for Packing Group I packagings;
(b) except as provided in paragraph (c), each cell or battery must be individually packed in an inner packaging inside an outer packaging and surrounded by cushioning material that is non-combustible, and non-conductive. Cells or batteries must be protected against short-circuiting;
(c) lithium batteries with a mass of 12 kg or greater and having a strong, impact resistant outer casing, or assemblies of such batteries, may be packed in strong outer packagings or protective enclosures not subject to the requirements of Section 6 of these Regulations. The batteries or battery assemblies must be protected agianst short circuiting; and
(d) a copy of the document of approval showing the quantity limitations must accompnay the consignment.
Irrespective of the limit specified in Column L of Table 4.2, the battery or battery assembly as prepared for transport may have a mass exceeding 35 kg G.
A89 (186) In determining the ammonium nitrate content, all nitrate ions for which a molecular equivalent of ammonium ions is present in the mixture shall be calculated as ammonium nitrate.
A90 (193) This entry may only be used for uniform ammonium nitrate based fertilizer mixtures of the nitrogen, phosphate or potash type, containing not more than 70% ammonium nitrate and not more than 0.4% total combustible/organic material calculated as carbon or with not more than 45% ammonium nitrate and unrestricted combustible material. Fertilizers within these composition limits are not subject to these Regulations if shown by the Trough Test (see UN Manual of Tests and Criteria Part III, subsection 38.2) not to be liable to self-sustaining decomposition.
A91 (198) A nitrocellulose solution containing 20% or less nitrocellulose may be transported under the requirements for “Paint”, UN 1263, UN 3066, UN 3469 or UN 3470, “Perfumery Products”, UN1266 or “Printing Ink”, UN 1210, as appropriate.
A92 (199) Lead compounds which, when mixed in a ratio of 1:1000 with 0.07 M (molar) hydrochloric acid and stirred for one hour at a temperature of 23ºC ± 2ºC, exhibit a solubility of 5% or less (see ISO 3711:1990 “Lead chromate pigments and lead chromate-molybdate pigments – Specifications and methods of tests”) are considered insoluble and are not subject to these Regulations unless they meet the criteria for inclusion in another hazard class or division.
A93 A heat-producing article is not subject to these Regulations when the heat-producing component or the energy source is removed to prevent unintentional functioning during transport.
The words “Not Restricted” and the Special Provision number must be included in the description of the substance on the Air Waybill as required by 8.2.6, when an Air Waybill is issued.
A94 Batteries or cells containing sodium must not contain dangerous goods other than sodium, sulphur and/or polysulphides. Batteries or cells must not be offered for transport at a temperature such that liquid elemental sodium is present in the battery or cell unless approved and under conditions established by the appropriate national authority.
Cells must consist of hermetically sealed metal casings which fully enclose the dangerous goods and which are so constructed and closed as to prevent the release of the dangerous goods under normal conditions of transport.
Batteries must consist of cells secured within and fully enclosed by a metal casing so constructed and closed as to prevent the release of the dangerous goods under normal conditions of transport.
A95 (203) This entry is not to be used for Polychlorinated biphenyls (UN 2315).
A96 (196) Only formulations which, in laboratory testing, neither detonate in the cavitated state nor deflagrate, which show no effect when heated under confinement and which exhibit no explosive power may be transported under this entry. The formulation must also be thermally stable, i.e. the SADT is 60ºC or higher for a 50 kg package. Formulations not meeting these criteria must be transported under the appropriate provisions of Division 5.2.
A97 These
entries must be used for substances which are hazardous to the environment but
do not meet the classification criteria of any other class or other substance
within Class 9. This must be based on the criteria as indicated in 3.9.2.4.
This designation may also be used for wastes not otherwise subject to these
Regulations but which are covered under the Basle
Convention on the Control of Transboundary Movements of Hazardous Wastes and
their Disposal.
A98 Aerosols, gas cartridges and receptacles, small, containing gas with a capacity not exceeding 50 ml, containing no constituents subject to these Regulations other than a Division 2.2 gas, are not subject to these Regulations unless their release could cause extreme annoyance or discomfort to crew members so as to prevent the correct performance of duties.
The words “Not Restricted” and the Special Provision number must be included in the description of the substance on the Air Waybill as required by 8.2.6, when an Air Waybill is issued.
A99 Irrespective of the per package quantity limit for cargo aircraft specified in Column L of the List of Dangerous Goods (Subsection 4.2), and in Section I of Packing Instructions 965, 966, 967, 968, 969 or 970, a lithium battery or battery assembly (UN 3090 or UN 3480), including when packed with, or contained in equipment (UN 3091 or UN 3481) that meets the other requirements of Section I of the applicable packing instruction may have a mass exceeding 35 kg, if approved by the appropriate authority of the State of origin. A copy of the document of approval must accompany the consignment.
A100 (243) Gasoline, motor spirit and petrol for use in spark-ignition (e.g. in automobiles, stationary engines and other engines) must be assigned to this entry regardless of variation in volatility.
A101 (227) When phlegmatized with water and inorganic inert material, the content of urea nitrate may not exceed 75% by weight and the mixture must not be capable of being detonated by the Series 1 type (a) test in the UN Manual of Tests and Criteria, Part I.
A102 (244) This listing includes aluminium dross, aluminium skimmings, spent cathodes, spent potliner and aluminium salt slags.
A103 Flammable liquefied gases must be contained within refrigerating machine components. These components must be designed and tested to at least three times the working pressure of the machinery . The refrigerating machines must be designed and constructed to contain the liquefied gas and preclude the risk of bursting or cracking of the pressure retaining components during normal conditions of transport. Refrigerating machines and refrigerating machine components are considered not subject to these Regulations if containing less than 100 g of flammable, non-toxic, liquefied gas.
A104 A toxic subsidiary risk label, although not required by these Regulations, may be applied.
A105 (242) Sulphur is not subject to these Regulations when it has been formed to a specific shape, e.g. prills, granules, pellets, pastilles or flakes.
A106 This entry may only be used for samples of chemicals taken for analysis in connection with the implementation of the Chemical Weapons Convention.
They may be transported on a passenger or cargo aircraft providing prior approval has been granted by the appropriate authority of the State of origin or the Director General of the Organization for the Prohibition of Chemical Weapons. For instructions on shipping such samples contact the national competent authority.
The substance is assumed to meet the criteria of Packing Group I for Division 6.1. Subsidiary risk labelling is not required.
A copy of the document of approval, showing the quantity limitations and the packing requirements, must accompany the consignment.
Note: The transport of substances under this description must be in accordance with chain of custody and security procedures specified by the Organization for the Prohibition of Chemical Weapons.
A107 This entry only applies to machinery or apparatus containing dangerous goods as a residue or as an integral element of the machinery or apparatus. It must not be used for machinery or apparatus for which a proper shipping name already exists in Subsection 4.2 – List of Dangerous Goods.
A108 The provisions of Special Provision A1 apply to this entry for Packing Group I only.
A109 Not used.
A110 (226) Formulations of these substances containing 30% or more non-volatile, non-flammable phlegmatizer are not subject to these Regulations.
A111 Oxygen generators, chemical, which have passed their expiration date, are unserviceable, or which have been used are forbidden for transport.
A112 Consumer commodities may only include substances of Class 2 (non-toxic aerosols only), Class 3 (Packing Group II or III), Division 6.1 (Packing Group III only), UN 3077, UN 3082 and UN 3175, provided such substances do not have a subsidiary risk. Dangerous goods that are forbidden for transport aboard passenger aircraft must not be transported as consumer commodities.
A113 (279) The substance is assigned to this classification or packing group based on human experience rather than the strict application of classification criteria set out in these Regulations.
A114 (283) Articles, containing gas intended to function as shock absorbers, including impact energy absorbing devices or pneumatic springs are not subject to these Regulations provided:
(a) each article has a gas space capacity not exceeding 1.6 L and a charge pressure not exceeding 280 bar where the product of the capacity (litres) and charge pressure (bars) does not exceed 80 (i.e. 0.5 L gas space and 160 bar charge pressure, 1 L gas space and 80 bar charge pressure, 1.6 L gas space and 50 bar charge pressure, 0.28 L gas space and 280 bar charge pressure);
(b) each article has a minimum burst pressure of 4 times the charge pressure at 20ºC for products not exceeding 0.5 L gas space capacity and 5 times charge pressure for products greater than 0.5 L gas space capacity;
(c) each article is manufactured from material which will not fragment upon rupture;
(d) each article is manufactured in accordance with a quality assurance standard acceptable to the appropriate national authority; and
(e) the design type has been subjected to a fire test demonstrating that pressure in the article is relieved, by means of a fire degradable seal or other pressure relief device such that the article will not fragment and the article does not rocket.
A115 (280) This entry applies to articles which are used as life saving vehicle air bag inflators or air bag modules or seat-belt pretensioners, and which contain dangerous goods of Class 1 or dangerous goods of other classes and when transported as component parts and when these articles are presented for transport have been tested in accordance with Test series 6 (c) of Part I of the UN Manual of Tests and Criteria with no explosion of the device, no fragmentation of the device casing or pressure vessel and no projection hazard nor thermal effect which would significantly hinder fire-fighting or other emergency response efforts in the immediate vicinity.
A116 An oxygen generator, chemical, when containing an explosive actuating device must only be transported under this entry when excluded from Class 1 in accordance with 3.1.1(b) of these Regulations.
A117 Wastes transported under UN 3291 are wastes derived from the medical treatment of humans or animals or from bio-research, where there is a relatively low probability that infectious substances are present. Waste infectious substances, which can be specified, must be assigned to UN 2814 or UN 2900. Decontaminated wastes, which previously contained infectious substances, may be considered as not subject to these Regulations unless the criteria of another Class or Division are met.
A118 Items classified as explosives must be removed from vehicles and transported in accordance with the provisions of these Regulations unless authorized by the appropriate national authority under the written conditions established by that authority. In such circumstances, vehicles may be transported on cargo aircraft only.
Note: This Special Provision does not apply where the explosives are a smoke candle installed as a permanent part of the vehicle or are part of an assembly classified as dangerous goods of other than Class 1, e.g. Air bag inflators, Air bag modules and Seat-belt pretensioners (UN 3268), Fire extinguishers (UN 1044), etc. Additionally this Special Provision does not apply in the case of Air bag modules and Air bag inflators and Seat-belt pretensioners (UN 0503) installed in the vehicle.
A119 Irrespective
of the limit specified in Column L of Subsection 4.2 – List of Dangerous Goods,
Dedicated Handling Devices (DHD) meeting the requirements of Packing
Instruction 961 as prepared for transport, may have a gross weight not
exceeding 1,000 kg.
A120 This entry includes but is not limited to automobiles, motorcycles, aircraft, boats, snowmobiles, jet skis, etc.
A121 Not used.
A122 (286) Nitrocellulose membrane filters covered by this entry, each with a mass not exceeding 0.5 g, are not subject to these Regulations when contained individually in an article or a sealed packet.
A123 This entry applies to Batteries, electric storage, not otherwise listed in Subsection 4.2 – List of Dangerous Goods. Examples of such batteries are: alkali-manganese, zinc-carbon, nickel-metal hydride and nickel-cadmium batteries. Any electrical battery or battery powered device, equipment or vehicle having the potential of dangerous evolution of heat must be prepared for transport so as to prevent
(a) a short-circuit (e.g. in the case of batteries, by the effective insulation of exposed terminals; or, in the case of equipment, by disconnection of the battery and protection of exposed terminals) is forbidden from transport; and
(b) accidental activation
The words “Not Restricted” and the Special Provision number must be included in the description of the substance on the Air Waybill as required by 8.2.6, when an Air Waybill is issued.
A124 Not used.
A125 (293) The following definitions apply to matches:
(a) Fusee matches are matches, the heads of which are prepared with a friction sensitive igniter composition and a pyrotechnic composition which burns with little or no flame, but with intense heat;
(b) Safety matches are combined with or attached to the box, book or card that can be ignited by friction only on a prepared surface;
(c) Strike anywhere matches are matches that can be ignited by friction on a solid surface;
(d) Wax Vesta matches are matches that can be ignited by friction either on a prepared surface or on a solid surface.
A126 Not used.
A127 Not used.
A128 (153) This entry only applies if it is demonstrated, on the basis of tests, that the substances, when in contact with water are not combustible nor show a tendency to auto-ignition and that the mixture of gases evolved is not flammable.
A129 (252) Provided the ammonium nitrate remains in solution under all conditions of transport, aqueous solutions of ammonium nitrate, with not more than 0.2% combustible material, in a concentration not exceeding 80% are not subject to these Regulations.
A130 When this radioactive material meets the definitions and criteria of other classes or divisions as defined in Section 3, it must be classified in accordance with the following:
(a) where the substance meets the criteria for dangerous goods in excepted quantities as set out in 2.6, the packagings must be in accordance with 2.6.5 and meet the testing requirements of 2.6.6. All other requirements applicable to radioactive material, excepted packages as set out in 10.0.1.5 apply without reference to the other class or division;
(b) where the quantity exceeds the limits specified in 2.6.4 the substance must be classified in accordance with the predominant subsidiary risk. The Shipper’s Declaration must describe the substance with the proper shipping name and UN number applicable to the other class supplemented with the name applicable to the radioactive excepted package according to Column B in Subsection 4.2 – List of Dangerous Goods, and must be transported in accordance with the provisions applicable to that UN number. An example of the sequence of information shown on the Shipper’s Declaration is:
UN1993, Flammable liquid, n.o.s. (ethanol and toluene mixture), Radioactive material, excepted package-limited quantity of material, Class 3, PG II;
The radioactive material, excepted package label (Figure 10.7.8.A) is not required on packages meeting the conditions set out in this sub-paragraph. In addition, to aid acceptance Special Provision A130 must be shown in the authorizations column on the Shipper’s Declaration. In addition, the requirements of 10.3.11.1 apply;
(c) substances classified in accordance with subparagraph (b) are not permitted to be shipped in accordance with the limited quantity provisions set out in 2.7;
(d) when the substance meets a special provision that exempts this substance from all dangerous goods provisions of the other classes it must be classified in accordancce with the applicable UN number of class 7 and all requirements specified in 10.0.1.5 apply.
A131 Glass inner receptacles (such as ampoules or capsules) intended only for use in sterilization devices, when containing less than 30 mL of ethylene oxide per inner packaging with not more than 300 mL per outer packaging, may be transported in accordance with the provisions in Subsection 2.6, irrespective of the indication of “E0” in Column F of Table 4.2 provided that:
(a) after filling, each glass inner receptacle has been determined to be determined to be leak-tight by placing the glass inner receptacle in a hot water bath at a temperature, and for a period of time, sufficient to ensure that an internal pressure equal to the vapour pressure of ethylene oxide at 55ºC is achieved. Any glass inner receptacle showing evidence of leakage, distortion or other defect under this test must not be transported under the terms of this special provision;
(b) in addition to the packaging required by 2.6.5, each glass inner receptacle is placed in a sealed plastic bag compatible with ethylene oxide capable of containing the contents in the event of breakage or leakage of the glass inner receptacle; and
(c) each glass inner receptacle is protected by a means of preventing puncture of the plastic bag (e.g. sleeves or cushioning) in the event of damage to the packaging (e.g. by crushing).
A132 (204) Articles containing smoke-producing
substance(s), corrosive, according to the criteria for Class 8 must be labelled
with a “Corrosive” subsidiary risk label.
A133 (311) Substances must not be
transported under this entry unless approved by the appropriate national
authority on the basis of the results of appropriate tests according to Part I
of the UN Manual of Tests and Criteria. Packaging must ensure that the
percentage of diluent does not fall below that stated in the appropriate
authority approval at any time during transport.
A134 (312) Vehicles or machinery powered by a fuel cell engine must be consigned under the entries UN 3166 Vehicle, fuel cell, flammable gas powered or UN 3166 Vehicle, fuel cell, flammable liquid powered, or UN 3166 Engine, fuel cell, flammable gas powered or UN 3166 Engine, fuel cell, flammable liquid powered, as appropriate. These entries include hybrid electric vehicles powered by both a fuel cell and an internal combustion engine with wet batteries, sodium batteries or lithium batteries, transported with the battery(ies) installed.
Other vehicles which contain an internal combustion engine, must be consigned under the entries UN 3166 Vehicle, flammable gas powered or UN 3166 Vehicle, flammable liquid powered, as appropriate. These entries include hybrid electric vehicles powered by both an internal combustion engine and wet batteries, sodium batteries or lithium batteries, transported with the battery(ies) installed.
A135 Not used.
A136 (314) These substances are liable to
exothermic decomposition at elevated temperatures. Decomposition can be
initiated by heat or by impurities (e.g. powdered metals (iron, manganese,
cobalt, magnesium) and their compounds).
During the course of transport, these
substances must be shaded from direct sunlight and all sources of heat and be
placed in adequately ventilated areas.
A137 (315) This entry must not be used for
Division 6.1 substances that meet the inhalation toxicity criteria for Packing
Group I described in 3.6.1.5.3.2.
A138 (316) This entry applies only to calcium
hypochlorite, dry, when transported in non friable tablet form.
A139 (317) “Fissile-excepted” applies only to
those packages complying with section 10.6.2.4.
A140 (318) Notwithstanding the “«” against the proper shipping name in Column
B, the technical names need not be shown on the package. When the infectious
substances to be transported are unknown, but suspected of meeting the criteria
for inclusion in Category A and assigned to UN 2814 or UN 2900, the words
“suspected category A infectious substance” must be shown, in parentheses,
following the proper shipping name on the Shipper’s Declaration for Dangerous
Goods, but not on the outer packagings.
A141 Not
used.
A142 Not
used.
A143 (321) These storage systems must always be
considered as containing hydrogen.
A144 Protective Breathing Equipment (PBE)
containing a small chemical oxygen generator for use by air crew members may be
transported on passenger aircraft in accordance with Packing Instruction 565
subject to the following conditions:
(a) the
PBE must be serviceable and contained in the manufacturer’s original unopened
inner packaging (i.e. vacuum sealed bag and protective container);
(b) the
PBE may only be consigned by, or on behalf of, an operator in the event that a
PBE(s) has been rendered unserviceable or has been used and there is a need to
replace such items so as to restore the number of PBEs on an aircraft to that
required by pertinent airworthiness requirements and operating regulations;
(c) a
maximum of 2 PBEs may be contained in a package;
(d) the
statement “Air crew Protective Breathing Equipment (smoke hood) in accordance
with Special Provision A144” must be:
1. included on the Shipper’s Declaration for
Dangerous Goods;
2. marked adjacent to the proper shipping
name on the package.
If the above conditions are met, the
requirements of Special Provision A1 do not apply. All other requirements
applicable to chemical oxygen generators must apply except that the “cargo
aircraft only” handling label must not be displayed.
A145 Waste aerosols are prohibited from air
transport.
A146 (328) This entry applies to fuel cell
cartridges including when contained in equipment or packed with equipment. Fuel
cell cartridges installed in or integral to a fuel cell system are regarded as
contained in equipment. Fuel cell cartridge means an article that stores fuel
for discharge into the fuel cell through a valve(s) that controls the discharge
of fuel into the fuel cell. Fuel cell cartridges, including when contained in
equipment, must be designed and constructed to prevent fuel leakage during
normal conditions of transport.
Fuel cell cartridge design types
using liquids as fuels, must pass an internal pressure test at a pressure of
100 kPa (gauge), without leakage.
Except for fuel cell cartridges
containing hydrogen in metal hydride which must be in compliance with A162,
each fuel cell cartridge design type, including fuel cell cartridges installed
in or integral to a fuel cell system, must be shown to pass a 1.2 m drop test
onto an unyielding surface in the orientation most likely to result in failure
of the containment system with no loss of contents.
A147 Not used.
A148 Not used.
A149 Not
used.
A150 An additional subsidiary risk hazard label
may be required by a Note found adjacent to the technical name entry in Table
C.2.
A151 When dry ice is used as a refrigerant for
other than dangerous goods loaded in a unit load device or other type of
pallet, the quantity limits per package shown in columns J and L in Section 4.2
for dry ice do not apply. In such case, the unit load device or other type of
pallet must be identified to the operator and must allow the venting of the
carbon dioxide gas to prevent a dangerous build up of pressure.
A152 Insulated packagings conforming to the
requirements of Packing Instruction 202 containing refrigerated liquid nitrogen
fully absorbed in a porous material are not subject to these Regulations provided
the design of the insulated packaging would not allow the build-up of pressure
within the container and would not permit the release of any refrigerated
liquid nitrogen irrespective of the orientation of the insulated packaging and
any outer packaging or overpack used is closed in a way that will not allow the
build-up of pressure within that packaging or overpack.
When used to contain substances not subject to these Regulations the words “Not Restricted” and the Special Provision number must be included in the description of the substance on the Air Waybill as required by 8.2.6, when an Air Waybill is issued.
A153 Not used.
A154 Lithium batteries identified by the
manufacturer as being defective for safety reasons, or that have been damaged,
that have the potential of producing a dangerous evolution of heat, fire or
short circuit are forbidden for transport (e.g. those being returned to the
manufacturer for safety reasons).
A155 (332) Magnesium nitrate hexahydrate is not subject to these Regulations.
A156 (333) Ethanol and gasoline, motor spirit or petrol mixtures for use in spark-ignition engines (e.g. in automobiles, stationary engines and other engines) must be assigned to this entry regardless of variations in volatility.
A157 (334) A fuel cell cartridge may contain an activator provided it is fitted with two independent means of preventing unintended mixing with the fuel during transport.
A158 (335) Mixtures of solids which are not subject to these Regulations and liquids or solids classified by the shippers as environmentally hazardous substances (UN 3077 and UN 3082) may be transported under this entry, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging is closed. Sealed packets and articles containing less than 10 mL of an environmentally hazardous liquid, absorbed into a solid material but with no free liquid in the packet or article, or containing less than 10 g of an environmentally hazardous solid, are not subject to these Regulations.
A159 (336) A single package of non-combustible solid LSA-II or LSA-III material must not contain an activity greater than 3,000 A2.
A160 (337) Type B(U) and Type B(M) packages, must not contain activities greater than the following:
(a) for low dispersible radioactive material: as authorized for the package design as specified in the certificate of approval;
(b) for special form radioactive material: 3,000 A1 or 100,000 A2, whichever is the lower; or
(c) for all other radioactive material: 3000 A2.
A161 (338) Each fuel cell cartridge transported under this entry and designed to contain a liquefied flammable gas must:
(a) be capable of withstanding, without leakage or bursting, a pressure of at least two times the equilibrium pressure of the contents at 55°C;
(b) not contain more than 200 mL of liquefied flammable gas with a vapour pressure not exceeding 1,000 kPa at 55°C; and
(c) pass the hot water bath test prescribed in 6.4.4.1.
A162 (339) Fuel cell cartridges containing hydrogen in a metal hydride transported under this entry must have a water capacity less than or equal to 120 mL.
The pressure in the fuel cell cartridge must not exceed 5 MPa at 55°C. The design type must withstand, without leaking or bursting, a pressure of two (2) times the design pressure of the cartridge at 55°C or 200 kPa more than the design pressure of the cartridge at 55°C, whichever is greater. The pressure at which this test is conducted is referred to in the drop test and the hydrogen cycling test as the “minimum shell burst pressure”.
Fuel cell cartridges must be filled in accordance with procedures provided by the manufacturer. The manufacturer must provide the following information with each fuel cell cartridge:
(a) inspection procedures to be carried out before initial filling and before refilling of the fuel cell cartridge;
(b) safety precautions and potential hazards to be aware of;
(c) method for determining when the rated capacity has been achieved;
(d) minimum and maximum pressure range;
(e) minimum and maximum temperature range; and
(f) any other requirements to be met for initial filling and refilling including the type of equipment to be used for initial filling and refilling.
The fuel cell cartridges must be designed and constructed to prevent fuel leakage under normal conditions of transport. Each cartridge design type, including cartridges integral to a fuel cell, must be subjected to and must pass the following tests:
Drop test
A 1.8 metre drop test onto an unyielding surface in four different orientations:
(a) vertically, on the end containing the shut-off valve assembly;
(b) vertically, on the end opposite to the shut-off valve assembly;
(c) horizontally, onto a steel apex onto a steel apex with a diameter of 38 mm, with the steel apex in the upward position; and
(d) at a 45° angle on the end containing the shut-off valve assembly.
There must be no leakage, determined by using a soap bubble solution or other equivalent means on all possible leak locations, when the cartridge is charged to its rated charging pressure. The fuel cell cartridge must then be hydrostatically pressurized to destruction. The recorded burst pressure must
exceed 85% of the minimum shell burst pressure.
Fire test
A fuel cell cartridge filled to rated capacity with hydrogen must be subjected to a fire engulfment test.
The cartridge design, which may include a vent feature integral to it, is deemed to have passed the fire test if:
(a) the internal pressure vents to zero gauge pressure without rupture of the cartridge; or
(b) the cartridge withstands the fire for a minimum of 20 minutes without rupture.
Hydrogen cycling test
This test is intended to ensure that a fuel cell cartridge design stress limits are not exceeded during use. The fuel cell cartridge must be cycled from not more than 5% rated hydrogen capacity to not less than 95% rated hydrogen capacity and back to not more than 5% rated hydrogen capacity. The rated charging pressure must be used for charging and temperatures must be held within the operating temperature range. The cycling must be continued for at least 100 cycles.
Following the cycling test, the fuel cell cartridge must be charged and the water volume displaced by the cartridge must be measured. The cartridge design is deemed to have passed the hydrogen cycling test if the water volume displaced by the cycled cartridge does not exceed the water volume displaced by an uncycled cartridge charged to 95% rated capacity and pressurized to 75% of its minimum shell burst pressure.
Production leak test
Each fuel cell cartridge must be tested for leaks at 15°C ± 5°C, while pressurized to its rated charging pressure. There must be no leakage, determined by using a soap bubble solution or other equivalent means on all possible leak locations.
Each fuel cell cartridge must be permanently marked with the following information:
(a) the rated charging pressure in megapascals (MPa);
(b) the manufacturer's serial number of the fuel cell cartridges or unique identification number; and
(c) the date of expiry based on the maximum service life (year in four digits; month in two digits).
A163 (340) Chemical kits, first aid kits and polyester resin kits containing dangerous goods in inner packagings which do not exceed the quantity limits for excepted quantities applicable to individual substances as specified in Column F of Table 4.2 may be transported in accordance with 2.6. Division 5.2 substances, although not individually authorized as excepted quantities in Table 4.2, are authorized in such kits and are assigned Code E2 (see 2.6.4.1).
A164 Any electrical battery or battery powered device, equipment or vehicle having the potential of a dangerous evolution of heat must be prepared for transport so as to prevent:
(a) a short circuit (e.g. in the case of batteries, by the effective insulation of exposed terminals; or in the case of equipment, by disconnection of the battery and protection of exposed terminals); and
(b) unintentional activation.
A165 This entry may only be used if the results of Test Series 6(d) of Part I of the UN Manual of Tests and Criteria have demonstrated that any hazardous effects arising from functioning are confined within the package (see 3.1.4.3).
A166 (343) This entry applies to crude oil containing hydrogen sulphide in sufficient concentration that vapours evolved from the crude oil can present an inhalation hazard. The packing group assigned must be determined by the flammability hazard and inhalation hazard, in accordance with the degree of danger presented.
A167 (344) The provisions of 6.4.4 must be met.
A168 Not used.
A169 (349) Mixtures of a hypochlorite with an ammonium salt are forbidden for transport. UN 1791 Hypochlorite solution is a substance of Class 8.
A170 (350) Ammonium bromate and its aqueous solutions and mixtures of a bromate with an ammonium salt are forbidden for transport.
A171 (351) Ammonium chlorate and its aqeous solutions and mixtures of a chlorate with an ammonium salt are forbidden for transport.
A172 (352) Ammonium chlorite and its aqeous solutions and mixtures of a chlorite with an ammonium salt are forbidden for transport.
A173 (353) Ammonium permanganate and its aqeous solutions and mixtures of a permanganate with an ammonium salt are forbidden for transport.
A174 (354) This substance is toxic by inhalation.
A175 (355) Oxygen cylinders for emergency use transported under this entry may include installed actuating cartridges (cartridges, power device of Division 1.4, Compatibility Group C or S), without changing the classification of Division 2.2 provided the total quantity of deflagrating (propellant) explosives does not exceed 3.2 g per oxygen cylinder. The cylinders with the installed actuating cartridges as prepared for transport must have an effective means of preventing inadvertent activation.
A176 (356) Metal hydride storage system(s) installed in conveyances or in completed conveyance components or intended to be installed in conveyances must be approved by the appropriate national authority before acceptance for transport. The Shipper’s Declaration must include an indication that the package was approved by the appropriate national authority or a copy of the approval must accompany each consignment.
A177 (357) Petroleum crude oil containing hydrogen sulphide in sufficient concentration that vapours evolved from the crude oil can present an inhalation hazard must be consigned under the entry UN 3494 Petrolem sour crude oil, flammable, toxic.
A178 Security type equipment such as attaché cases, cash boxes, cash bags, etc., incorporating dangerous goods, for example lithium batteries, gas cartridges, and/or pyrotechnic material, are not subject to these Regulations if the equipment complies with the following:
(a) the equipment must be equipped with an effective means of preventing accidental activation;
(b) if the equipment contains an explosive or an pyrotechnic substance or an explosive article, this article or substance must be excluded from Class 1 by the appropriate national authority of the State of Manufacture in compliance with 3.1.7.1;
(c) if the equipment contains lithium cells or batteries, these cells or batteries must comply with the following restrictions:
1. for a lithium metal cell, the lithium content is not more than 1 g;
2. for a lithium metal or lithium alloy battery, the aggregate lithium content is not more than 2 g;
3. for lithium ion cells, the Watt-hour rating is not more than 20 Wh;
4. for lithium ion batteries, the Watt-hour rating is not more than 100 Wh;
5. each cell or battery is of the type proven to meet the requirements of each test in the UN Manaual of Tests and Criteria, Part III, section 38.3;
(d) if the equipment contains gases to expel dye or ink, only gas cartridges and receptacles, small, containing gas with a capacity not exceeding 50 mL, containing no constituents subject to these Regulations other than a Division 2.2 gas, are allowed. The release of gas must not cause extreme annoyance or discomfort to crew members so as to prevent the correct performance of assigned duties. In case of accidental activation all hazardous effects must be confined within the equipment and must not produce extreme noise.
(e) security type equipment that is defective or that has been damaged is forbidden for transport.
The words “not restricted” and the special provision number must be included in the description of the substance on the Air Waybill as required by 8.2.6, when an Air Waybill is issued.
A179 For UN 3077, irrespective of the maximum net quantities specified in Columns J and L of Table 4.2, intermediate bulk containers (IBCs) with a maximum net quantity not exceeding 1 000 kg are permitted in accordance with Packing Instruction 956.
A180 Non-infectious specimens, such as specimens of mammals, birds, amphibians, reptiles, fish, insects and other invertebrates containing small quantities of UN 1170, UN 1198, UN 1987, or UN 1219 are not subject to these Regulations provided the following packing and marking requirements are met:
(a) specimens are:
(1) wrapped
in paper towel and/or cheesecloth moistened with alcohol or an alcohol solution
and then placed in a plastic bag that is heat-sealed. Any free liquid in the
bag must not exceed 30 mL; or
(2) placed in vials or other rigid containers with no more than 30 mL of alcohol or an alcohol solution;
(b) the prepared specimens are then placed in a plastic bag that is then heat-sealed;
(c) the bagged specimens are then placed inside a another plastic bag with absorbent material then heat-sealed.
(d) the finished bag is then placed in a strong outer packaging with suitable cushioning material;
(e) the total quantity of flammable liquid per outer packaging must not exceed 1 L; and
(f) the completed package is marked “scientific research specimens, not restricted Special Provision A180 applies”.
The words “not restricted”and the special provison number A180 must be included in the description of the substance on the Air Waybill as required by 8.2.6, when an Air Waybill is issued.
A181 When a package contains a combination of lithium batteries contained in equipment and lithium batteries packed with equipment, the package must be marked UN 3091 Lithium metal batteries packed with equipment or UN 3481 Lithium ion batteries packed with euipment as appropriate. If a package contains both lithium ion batteries and lithium metal batteries, the package must be marked as required for both battery types. However, button cell batteries installed in equipment (including circuit boards) need not be considered.
A182 Equipment containing only lithium batteries must be classified as either UN 3091 or UN 3481.
A183 Waste batteries and batteries being shipped for recycling or disposal are prohibited from air transport unless approved by the appropriate national authority of the State of Origin and the State of the Operator.
A202 For the purposes of providing life support for aquatic animals during transport, the appropriate authorities of the States of origin, destination and of the operator may approve the carriage of a cylinder containing Oxygen compressed, UN 1072, with the valves open to supply a controlled quantity of oxygen through a regulator into water containing the aquatic animals. The cylinder or cylinder valve must be fitted with a self-sealing device to prevent uncontrolled release of oxygen should the regulator malfunction or be broken or damaged. The oxygen cylinder must meet those parts of Packing Instruction 200 that apply, except for the need for valves to be closed. In addition, the following conditions apply as a minimum:
(a) the water container with the attached oxygen cylinder must be designed and constructed to withstand all anticipated loads;
(b) the water container with the oxygen supply operating must be tilt-tested at an angle of 45° in four directions from the upright, for a minimum duration of 10 minutes in each direction, without leakage of water;
(c) the oxygen cylinder and regulator must be restrained and protected within the equipment;
(d) the oxygen regulator used must have a maximum flow rate of not more than 5 L per minute;
(e) the oxygen flow rate to the container must be limited to that sufficient to provide life support to the aquatic animals;
(f) the quantity of oxygen provided must not exceed 150% of the oxygen required for the normal duration of air transport; and
(g) only one cylinder may be carried for each 15 m3 of gross cargo hold volume. Under no circumstances may the rate of oxygen flow from the cylinder exceed 1 L per minute per 5 m3 of gross cargo hold volume.
A224 For the purpose of transporting a symbolic flame, the appropriate authority of the States of origin, of destination and of the operator may approve the carriage of lamps fuelled by UN 1223 – Kerosene, or UN 3295 – Hydrocarbons, liquid, n.o.s., carried by a passenger as carry on baggage only.
Lamps must be of a “Davy” type or similar apparatus. In addition, the following conditions apply as a minimum:
(a) no more than four lamps may be carried on board the aircraft;
(b) lamps may contain no more fuel than the quantity adequate for the duration of the flight and the fuel must be contained in a leakproof reservoir;
(c) lamps must be adequately secured;
(d) whilst on board the aircraft, the lamps must be under the constant supervision of an accompanying person, who must not be a member of the operating crew;
(e) lamps may be lit by the accompanying person, but must not be refilled on board the aircraft;
(f) at least one fire extinguisher must be kept within reach of the accompanying person at all times. The accompanying person must be trained in the use of the extinguisher;
(g) the crew members of the aircraft must be given a verbal briefing about the carriage of the lamps and the pilot-in-command must be provided with a copy of the approval; and
(h) 9.5.1.1.1b), c), e), 9.5.1.2, 9.5.1.3 and 9.6.1 of these Regulations must apply.
A801 A technical name is not needed for this entry if it is a controlled substance and a national law or international Convention prohibits its disclosure (see 4.1.2.1(d)).